| Round Number | Date | Location | Home Team | Away Team | Result |
|---|---|---|---|---|---|
| 1 | 09/08/2019 20:00 | Anfield | Liverpool | Norwich | 4 - 1 |
| 2 | 17/08/2019 15:00 | St. Mary's Stadium | Southampton | Liverpool | 1 - 2 |
| 3 | 24/08/2019 17:30 | Anfield | Liverpool | Arsenal | 3 - 1 |
| 4 | 31/08/2019 17:30 | Turf Moor | Burnley | Liverpool | 0 - 3 |
| 5 | 14/09/2019 12:30 | Anfield | Liverpool | Newcastle | 3 - 1 |
| 6 | 22/09/2019 16:30 | Stamford Bridge | Chelsea | Liverpool | 1 - 2 |
| 7 | 28/09/2019 12:30 | Bramall Lane | Sheffield Utd | Liverpool | 0 - 1 |
| 8 | 05/10/2019 15:00 | Anfield | Liverpool | Leicester | 2 - 1 |
| 9 | 20/10/2019 16:30 | Old Trafford | Man Utd | Liverpool | 1 - 1 |
| 10 | 27/10/2019 16:30 | Anfield | Liverpool | Spurs | 2 - 1 |
| 11 | 02/11/2019 15:00 | Villa Park | Aston Villa | Liverpool | 1 - 2 |
| 12 | 10/11/2019 16:30 | Anfield | Liverpool | Man City | 3 - 1 |
| 13 | 23/11/2019 15:00 | Selhurst Park | Crystal Palace | Liverpool | 1 - 2 |
| 14 | 30/11/2019 15:00 | Anfield | Liverpool | Brighton | 2 - 1 |
| 15 | 04/12/2019 20:15 | Anfield | Liverpool | Everton | 5 - 2 |
| 16 | 07/12/2019 15:00 | Vitality Stadium | Bournemouth | Liverpool | 0 - 3 |
| 17 | 14/12/2019 12:30 | Anfield | Liverpool | Watford | 2 - 0 |
| 19 | 26/12/2019 20:00 | King Power Stadium | Leicester | Liverpool | 0 - 4 |
| 20 | 29/12/2019 16:30 | Anfield | Liverpool | Wolves | 1 - 0 |
| 21 | 02/01/2020 20:00 | Anfield | Liverpool | Sheffield Utd | 2 - 0 |
| 22 | 11/01/2020 17:30 | Tottenham Hotspur Stadium | Spurs | Liverpool | 0 - 1 |
| 23 | 19/01/2020 16:30 | Anfield | Liverpool | Man Utd | 2 - 0 |
| 24 | 23/01/2020 20:00 | Molineux Stadium | Wolves | Liverpool | 1 - 2 |
| 25 | 29/01/2020 19:45 | London Stadium | West Ham | Liverpool | 0 - 2 |
| 25 | 01/02/2020 15:00 | Anfield | Liverpool | Southampton | 4 - 0 |
| 26 | 15/02/2020 17:30 | Carrow Road | Norwich | Liverpool | 0 - 1 |
| 27 | 24/02/2020 20:00 | Anfield | Liverpool | West Ham | 3 - 2 |
| 28 | 29/02/2020 17:30 | Vicarage Road | Watford | Liverpool | 3 - 0 |
| 29 | 07/03/2020 12:30 | Anfield | Liverpool | Bournemouth | 2 - 1 |
| 30 | 21/06/2020 19:00 | Goodison Park | Everton | Liverpool | 0 - 0 |
| 31 | 24/06/2020 20:15 | Anfield | Liverpool | Crystal Palace | 4 - 0 |
| 32 | 02/07/2020 20:15 | Etihad Stadium | Man City | Liverpool | 4 - 0 |
| 33 | 05/07/2020 16:30 | Anfield | Liverpool | Aston Villa | 2 - 0 |
| 34 | 08/07/2020 20:15 | Amex Stadium | Brighton | Liverpool | 1 - 3 |
| 35 | 11/07/2020 15:00 | Anfield | Liverpool | Burnley | 1 - 1 |
| 36 | 15/07/2020 20:15 | Emirates Stadium | Arsenal | Liverpool | 2 - 1 |
| 37 | 22/07/2020 20:15 | Anfield | Liverpool | Chelsea | 5 - 3 |
| 38 | 26/07/2020 16:00 | St. James' Park | Newcastle | Liverpool | 1 - 3 |